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Transport Properties and Potential Energy Models for Monatomic Gases by Hui Li (
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Item specifics
- Condition
- ISBN-13
- 9780198888253
- Book Title
- Transport Properties and Potential Energy Models for Monatomic Ga
- ISBN
- 9780198888253
- Subject Area
- Science
- Publication Name
- Transport Properties and Potential Energy Models for Monatomic Gases
- Item Length
- 9.8 in
- Publisher
- Oxford University Press, Incorporated
- Subject
- Physics / General, Mechanics / Thermodynamics
- Series
- International Series of Monographs on Physics Ser.
- Publication Year
- 2024
- Type
- Textbook
- Format
- Hardcover
- Language
- English
- Item Height
- 0.9 in
- Item Width
- 6.9 in
- Item Weight
- 29 Oz
- Number of Pages
- 352 Pages
About this product
Product Information
The first two chapters of this book are an update and outgrowth of the monograph Nonequilibrium Phenomena in Polyatomic Gases published by OUP in 1990, and a response to considerable improvements in the experimental determination of the transport properties of dilute gases that have taken place during the past 30 years. The experimental determination has improved sufficiently that it has become necessary to carry out calculations at the level of the second Chapman-Cowling approximation in order to give computed results that lie within the current experimental uncertainties now being reported. Chapter 3 is devoted to realistic interatomic potential energy functions, and begins with a discussion of the need for more accurate representations of these functions. Direct inversion of both microscopic data (spectroscopic transition frequencies and atomic beam scattering) and bulk property data (pressure and acoustic second virial coefficients, transport properties) are discussed in detail. The quantum chemical ab initio determination of binary atomic interaction energies and their analytical representation are discussed, followed by a detailed considerations of the interaction energies between pairs of noble gas atoms. Chapter 4 is concerned with connections between theory and experiment, including a detailed discussion of pure noble gases and their binary mixtures. Chapter 5 focuses on how to obtain the spectroscopic and thermophysical properties of a specific molecular system theoretically step by step, and provides a reference for the specific theoretical calculation work.
Product Identifiers
Publisher
Oxford University Press, Incorporated
ISBN-10
0198888252
ISBN-13
9780198888253
eBay Product ID (ePID)
4062939313
Product Key Features
Publication Name
Transport Properties and Potential Energy Models for Monatomic Gases
Format
Hardcover
Language
English
Subject
Physics / General, Mechanics / Thermodynamics
Series
International Series of Monographs on Physics Ser.
Publication Year
2024
Type
Textbook
Subject Area
Science
Number of Pages
352 Pages
Dimensions
Item Length
9.8 in
Item Height
0.9 in
Item Width
6.9 in
Item Weight
29 Oz
Additional Product Features
Intended Audience
Scholarly & Professional
Lc Classification Number
Qc175.16.B6l5 2024
Table of Content
1. THE MONATOMIC BOLTZMANN EQUATION1.1. The Boltzmann equation for dilute monatomic gases1.2. Equations of change and collisional invariants1.3. Entropy production1.4. The equilibrium state1.5. Linearization of the Boltzmann equation1.6. The Boltzmann equations for mixtures2. SOLUTIONS OF THE BOLTZMANN EQUATION2.1. Chapman-Enskog solution for pure monatomic gases2.2. Chapman-Enskog solution for binary mixtures2.3. Matrix approximations for the inverse collision operator2.4. The transport coefficients2.5. Effective cross sections2.6. Dynamical models for binary atomic interactions2.7. The moment method2.8. Kinetic models3. REALISTIC INTERATOMIC POTENTIAL ENERGY FUNCTIONS3.1. The need for realistic potential energy functions3.2. The Mie/Lennard-Jones potential energy functions3.3. Hartree-Fock plus damped dispersion semi-empirical models3.4. Exchange-coulomb semi-empirical models3.5. Modern empirical multiproperty-fit potential energy functions3.6. Direct inversions of experimental data3.7. Ab initio calculation of potential energy functions3.8. Interactions between pairs of ground-term noble gas atoms3.9. Interactions involving open-shell atoms4. COMPARISON BETWEEN THEORY AND EXPERIMENT4.1. Comparison between theory and experiment4.2. Correlation concept4.3. Binary mixtures of noble gases5. FROM AB INITIO CALCULATIONS TO SPECTROSCOPIC AND THERMOPHYSICAL PROPERTIES5.1. Ab initio calculations5.2. Fitting of analytic potential energy functions5.3. Spectroscopic properties5.4. Thermophysical propertiesAppendix A. MATHEMATICAL APPENDICESA.1. Maxwellian averagesA.2. Special functionsA.3. Vectors and tensorsA.4. Spherical harmonics and spherical tensorsReferencesIndex
Dewey Decimal
546.75
Dewey Edition
23
Illustrated
Yes
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